High Performance Randomly Segmented Poly(Urethane Siloxane) and Poly(Imide Siloxane) Copolymers

Siloxane Copolymers for Nanoimprint Lithography**

Nanoimprint lithography (NIL) is a fabrication technology that offers high-throughput, ultrahigh resolution patterning at great cost savings compared to most competing next-generation radiative lithography methods. As a result of its rapid development in the past decade and its potential for sub-100 nm lithography, NIL has been listed by MIT’s Technology Review as one of ten emerging technologi...

Synthesis of telechelic vinyl / allyl functional siloxane copolymers with structural

Understanding siloxane functionalised ionic liquids.

In this paper we use ab initio theoretical methods in combination with experimental studies to investigate ion-pairs of the ionic liquid (IL) 1-methyl-3-pentamethyldisiloxymethylimidazolium chloride [(SiOSi)C(1)C(1)im]Cl, in order to deepen our understanding of the effects of functionalisation on an IL. In addition, we focus on the effect of the siloxy group on the viscosity. We establish that ...

Effect of Siloxane Segment Length on the Surface Composition of Polyimidesiloxane Copolymers and its Role in Adhesion by

A series of polyimidesiloxane (SIM) copolymers, based on a.co-aminopropylpoly(dimethylsiloxane)(PDMS),2,2-bis(4-[4-aminophenoxyl]phenyl)propane(BAPP)and 4,4'-oxydiphthalic-anhydride(ODPA) was synthesized in our laboratories. We investigated the effect of siloxane segment length on the surface composition of the SIM copolymers and its role in adhesion. The aim is to elucidate the correlation bet...

Inflammatory response to a novel series of siloxane-crosslinked polyurethane elastomers having controlled biodegradation.

A series of polyurethane polymers was synthesized with increasing proportions of silicone in the form of polydimethylsiloxane (PDMS) utilised as a cross-linking agent, based on an aromatic, non-biostable polyetherurethane (PEtU). Eight formulations ranging from 0-50% PDMS were constructed into porous and non-porous films. These were implanted subcutaneously in rats, both unstrained and 100% str...